IMA 2017-069a = belomarinaite

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Marco E. Ciriotti
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IMA 2017-069a = belomarinaite

Messaggio da Marco E. Ciriotti » lun 21 gen, 2019 20:17

Prossima pubblicazione.

Referenza:
▪ Filatov, S.K., Shablinskii, A.P., Vergasova, L.P., Saprikina, O.U., Bubnova, R.S., Moskaleva, S.V., Belousov, A.B. (2018): Belomarinaite KNa(SO4): A new sulphate from 2012-2013 Tolbachik Fissure eruption, Kamchatka Peninsula, Russia. Mineralogical Magazine, 82, (in press).

Abstract:
Belomarinaite, ideally KNaSO4, is a new sulphate mineral discovered in the Toludskoe lava field formed during Tolbachik Fissure eruption in 2012–2013. The mineral occurs as arborescent aggregates of tabular crystals (1×0.3×0.1 mm3) comprising hematite impurities. The average size of the aggregates is 0.5–0.7 mm. The empirical formula is (K0.95Na0.92Cu0.04)S1.01O4. The crystal structure of belomarinaite was determined using single-crystal X-ray diffraction data: space group P3m1, a = 5.6072(3), c = 7.1781(4) Å, V = 195.45(2) Å3, Z = 2, R1 = 2.6%. In the crystal structure of belomarinaite, there are six cation sites: the [4]S(1,2) sites are occupied by S, the [6]Na and [12]K sites are occupied by Na and K, respectively, giving Na0.5K0.5 apfu and the [10]M1 and [10]M2 sites are occupied by Na0.80K0.20 and K0.80Na0.20 apfu, respectively. The crystal structure is a framework of SO4 tetrahedra, Na octahedra and K, M1 and M2 polyhedra. Belomarinaite is isostructural with the synthetic compound KNaSO4. In belomarinaite, Na and K are disordered over M1 and M2 sites; in its synthetic analogue, Na and K are ordered over M1 and M2 sites, respectively. Its Mohs’ hardness is 2–3. The mineral is uniaxial (+), ω = 1.485(3), ε = 1.488(3) (λ = 589 nm). The strongest lines of the X-ray powder diffraction pattern (d, Å (I, %) (hkl)) are: 4.022 (31) (101); 3.591 (26) (002); 2.884 (74) (102); 2.800 (100) (110); 2.391 (16) (003); 2.296 (8) 201; 2.008 (38) (022); and 1.634 (10) (212). The mineral was named in honour of Russian volcanologist Marina Gennadievna Belousova (b. 1960) for her significant contributions to the monitoring of the Tolbachik Fissure eruption.
Marco E. Ciriotti

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