Formation of saponite by hydrothermal alteration of metal oxides: implication for the rarity of hydrotalcite

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Marco E. Ciriotti
Messaggi: 25920
Iscritto il: ven 25 giu, 2004 11:31
Località: via San Pietro, 55 I-10073 Devesi/Cirié TO - Italy
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Formation of saponite by hydrothermal alteration of metal oxides: implication for the rarity of hydrotalcite

Messaggio da Marco E. Ciriotti » mar 07 mag, 2019 10:37

Prossima pubblicazione.

Referenza:
▪ Tao, Qi, Zeng, Q., Chen, M., He, H., Komarneni, S. (2019): Formation of saponite by hydrothermal alteration of metal oxides: implication for the rarity of hydrotalcite. American Mineralogist, 104, (in press).
Marco E. Ciriotti

«Things are interesting only in so far as they relate themselves to other things»

Avatar utente
Marco E. Ciriotti
Messaggi: 25920
Iscritto il: ven 25 giu, 2004 11:31
Località: via San Pietro, 55 I-10073 Devesi/Cirié TO - Italy
Contatta:

Re: Formation of saponite by hydrothermal alteration of metal oxides: implication for the rarity of hydrotalcite

Messaggio da Marco E. Ciriotti » lun 12 ago, 2019 14:41

Pubblicazione effettuata.

Referenza:
▪ Tao, Qi, Zeng, Q., Chen, M., He, H., Komarneni, S. (2019): Formation of saponite by hydrothermal alteration of metal oxides: implication for the rarity of hydrotalcite. American Mineralogist, 104, 1156–1164.

Abstract:
Conversion of hydrotalcite (Ht) to saponite was observed by hydrothermal alkaline alteration of metal oxides. The conversion was through a pathway of hydration-dissolution-precipitation. It involved several critical steps, including the construction of Ht from metal oxides, dissolution of Al3+ from Ht, condensation of metasilicate anions with Ht, and finally crystallization of saponite. The condensation was favored by relatively low Mg/Al ratios of Ht, along with high concentrations of Al3+ and silicate oligomers in the environment, resulting in highly crystalline saponite. The latter conversion was greatly accelerated by the isomorphous substitution of Al3+ for Si4+ in silicate oligomers. The substitution generated the extra negative charge and led to the aforementioned condensation with Ht surface, thereby promoting the formation of saponite TOT layers. During the process, CO2 is an indispensable component. Initially intercalated as CO32– to form Ht, CO2 was subsequently eliminated from the solid phase, and saponite formed when the layer charge was reversed. Thus, this study presents a novel formation mechanism of saponite from metal oxides via hydrotalcite and contributes to a better understanding of the crystallization, chemical stability, and transformation of Ht to saponite. The results are also relevant to evaluating metal availability and carbon cycling on the surface of the Earth.
Marco E. Ciriotti

«Things are interesting only in so far as they relate themselves to other things»

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