IMA 2020-029 = magnesiohögbomite-6N12S

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Marco E. Ciriotti
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IMA 2020-029 = magnesiohögbomite-6N12S

Messaggio da Marco E. Ciriotti » mer 31 mar, 2021 10:13

Prossima pubblicazione.

Referenza:
▪ Lykova, I., Rowe, R., Poirier, G., Giester, G., Helwig, K. (2021): Magnesiohögbomite-6N12S, Mg5Al11TiO23(OH), a new högbomite group mineral from the DeWitts Corners, Ontario, Canada. Mineralogical Magazine, 85, (in press).

Abstract:
new o it -group mineral magnesiohögbomite-6N12S, ideally Mg5Al11TiO23(OH), was found in calcite “vein in dikes” at the DeWitts Corners occurrence, lots 10 and 11, concession 1, Bathurst Township, Ontario, Canada. It forms tabular and short-prismatic crystals up to 5 mm in size. The major forms are pinacoid {0001} and hexagonal pyramid {11 1}, sometimes modified by hexagonal prism {11 0}. The associated minerals are magnesiohögbomite-2N3S, spinel, corundum, diopside, magnesio-hastingsite, pargasite, clinochlore and calcite. Magnesiohögbomite-6N12S is dark brown to black with brown streak and vitreous lustre. It has no cleavage, and its fracture is uneven. The Mohs hardness is 6½. Dcalc is 3.87 g/cm3. The IR spectrum is reported. The composition (wt.%) is MgO 13.09, ZnO 0.46, FeO 11.91, Fe2O3 6.84, Al2O3 62.70, TiO2 4.44, H2O 0.99, total 100.43. The empirical formula calculated on the basis of 17 cations, excluding H+, is (Mg2.95Fe2+1.51Al0.49Zn0.05)Σ5(Al10.71Fe3+0.78Ti0.51)Σ12O23(OH). The simplified formula is (Mg,Fe)5(Al,Fe,Ti)12O23(OH). The mineral is trigonal, R3 ̅m, a = 5.7194(2), c = 83.069(5) Å, V = 2353.3(2) Å3 and Z = 6. The strongest reflections of the powder X-ray diffraction pattern [d,Å(I)(hkl)] are: 2.921(26)(0.1.23), 2.863(49)(110), 2.687(29)(0.1.26), 2.547(31)(0.1.-28), 2.434(100)(1.1.18). The crystal structure was solved and refined from single-crystal X-ray diffraction data to R1 = 0.022. It is composed of alternating spinel (S) and nolanite (N) modules in the sequence 3 × (NSSNSS). The sequence of cubic ‘c’ and exagonal “h” closed-packed oxygen layers is 3 × (cccccchcccch). It is the first polysome in the högbomite it group with such a sequence.

NdR: Secondo me una conferma con Mössbauer delle quantità di Fe2+ e Fe3+ sarebbe stata opportuna.
Marco E. Ciriotti

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